The Paton Welding Journal, 2026, #7, 26-33 pages
Effect of vacuum annealing on the structure of high-temperature two-phase titanium (α+β)-alloy
V.Yu. Bilous1
, E.L. Vrzhizhevskyi1
, R.V. Selin1
, L.M. Radchenko1
, S.L. Antoniuk2
1E.O. Paton Electric Welding Institute of the NASU.
11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine.
E-mail: belousvy@gmail.com
2SC “O.K.Antonov ANTK”, 1 Mriya Str., 03062, Kyiv, Ukraine
Abstract
High-temperature two-phase (α+β) titanium alloys can exhibit high performance characteristics when used in aircraft engines.
To expand the scope of application or to repair components made of the two-phase VT9 alloy, it is advisable to consider the
possibility of using vacuum annealing to treat blanks or components after machining or welding. This study investigated the
effect of vacuum annealing at 950 °C on the microstructure of sheets made of the VT9 titanium (α+β) alloy. Sheets of the
VT9 titanium (α+β) alloy, 10 mm thick, were subjected to vacuum annealing at 950 °C for 1 hour and then cooled with the
furnace. The microstructure of the samples of the heat-treated two-phase (α+β) titanium alloy VT9 in the as-received condition
is homogeneous, finely dispersed and consists of α-phase particles with a thickness of 2–4 μm and a length of 2–20 μm. The
microstructure of the metal samples after vacuum annealing followed by cooling with the furnace is homogeneous and consists
of α-phase particles with a thickness of 2–6 μm and a length of up to 20 μm. An increase in the size of the α-phase is observed,
associated with its coagulation process. Vacuum annealing at 950 °C led to a decrease in the number of dispersed particles in
the metal structure and an increase in the size of α-phase particles due to coagulation during slow cooling. The amount of the
β-phase in the high-temperature (α+β) titanium alloy VT9 decreases to 15–22 %. Such structural changes can lead to a decrease
in the strength properties of the alloy and an increase in its impact toughness, which contributes to improved performance
characteristics of components made of the VT9 alloy.
Keywords: titanium alloy, two-phase (α+β) alloys, microstructure, vacuum annealing, α-phase, β-phase
Received: 10.04.2026
Received in revised form: 11.05.2026
Accepted: 13.07.2026
References
1. Firstov, S.O., Kulak, L.D., Kuzmenko, M.M., Shevchenko,
O.M. (2018) Alloys of Ti–Al–Zr–Si system for high-temperature
operation. Fizyko-Khimichna Mehanika Materialiv,
54(6), 30–35 [in Ukrainian]. http://jnas.nbuv.gov.ua/article/UJRN-0000958917
2. Shichen, Sun, Hongze, Fang, Yili, Li et al. (2023) Formation
mechanism and effect on the mechanical properties of TiSi
phase for Ti–5Al–5Mo–5Cr–3Nb–2Zr alloyed by silicon.
J. of Alloys and Compounds, 938(25), 168510. DOI: https://doi.org/10.1016/j.jallcom.2022.168510
3. Gomez-Gallegos, A., Mandal, P., Gonzalez, D. et
al. (2018)
Studies on titanium alloys for aerospace application. Defect
and Diffusion Forum, 385, 419–423. DOI: https://doi.org/10.4028/www.scientific.net/DDF.385.419
4. Williams, J.C., Boyer, R.R. (2020) Opportunities and issues
in the application of titanium alloys for aerospace components.
Metals, 10(6), 705. DOI: https://doi.org/10.3390/met10060705
5. Mantione, J., Garcia-Avila, M., Arnold, M. et al. (2020) Properties
of novel high temperature titanium alloys for aerospace
applications. In: Proc. of the MATEC Web of Conf., 321, 04006.
DOI: https://doi.org/10.1051/matecconf/202032104006
6. Solonina, O.P., Glazunov, S.G. (1973) High-temperature titanium
alloys. Moscow, Metallugiya.
7. Narushima, T., Sugizaki, Y. (2020) Recent activities of titanium
research and development in Japan. In: Proc. of
the MATEC Web of Conf., 321, 01004. DOI: https://doi.org/10.1051/matecconf/202032101004
8. Akhonin, S.V., Severin, A.Yu., Berezos, V.O. et al. (2021) Investigations
of the quality of wrought semi-finished products
of VT9 titanium alloy produced by electron beam melting.
Suchasna Elektrometalurhiya, 4, 20–24. DOI: https://doi.org/10.37434/sem2021.04.03
9. Kaibyshev, O.A., Lutfullin, R.Ya., Salishchev, G.A. (1985)
Microstructural changes in heat treatment and hot deformation
of VT9 titanium alloy with lamellar microstructure.
Fizika Metallov i Metallovedenie, 59(3), 578–583.
10. Skripalenko, M.M., Galkin, S.P., Karpov, B.V. et al. (2019)
Forming features and properties of titanium alloy billets after
radial-shear rolling. Materials, 12, 3179. DOI: https://doi.org/10.3390/ma12193179
11. Yadav, P., Saxena, K.K. (2020) Effect of heat-treatment on
microstructure and mechanical properties of Ti alloys: An
overview. Materials Today: Proceedings, 26, 2546–2557.
DOI: https://doi.org/10.1016/j.matpr.2020.02.541
12. Berdin, V.K., Karavaeva, M.V., Nurieva, S.K. (2002) Influence
of dispersity of lamellar microstructure on fragmentation
of α-plates during hot deformation of VT9 titanium alloy. Materialovedenie,
12, 47–53.
13. Jian Zhou, Xia Li, Chaoyi Ding et al. (2025) Deformation response
analysis of Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy under
electromagnetic shock treatment via nanoindentation. Materials
Characterization, Pt A, 229, 115551, DOI: https://doi.org/10.1016/j.matchar.2025.115551
14. Chai, Zaixian, Wang, William, Ren, Yong et al. (2024) Hot
deformation behavior and microstructure evolution of TC11
dual-phase titanium alloy. Materials Science and Engineering:
A, 898, 146331. DOI: https://doi.org/10.1016/j.msea.2024.146331
15. Akhonin, S.V., Pikulin, A.N., Klochai, V.V., Ryabtsev, A.D.
(2019) Electron-beam surface treatment of titanium alloy ingots.
Pt 1. Metallurgist, 63(1–2), 183–191. DOI: https://doi.org/10.1007/s11015-019-00808-9
16. Vodopyanova, O.V., Postylyakov, A.Yu., Shvarts, D.L. et al.
(2022) Evaluation of VT6 and VT9 α+β titanium alloys spreading
features during flat rolling. In: Proc. of the AIP Conf.,
2456(1), 020039. DOI: https://doi.org/10.1063/5.0074585
17. Jia, X., Yang, Y., Di, R. (2025) Ti–6.5Al–3.5Mo–1.5Zr–0.3Si
Alloy fabricated by laser melting deposition: Microstructure
evolution and anisotropy. J. of Materials Engineering and
Performance. DOI: https://doi:10.1007/s11665-025-12862-3
18. Pushilina, N.S., Kashkarov, E.B., Syrtanov, M.S. et al. (2018)
Microstructure and properties of Ti–6.5Al–3.5Mo–1.5Zr–
0.3Si parts produced by electron beam melting. J. of Physics:
Conf. Series, 1115(4), 042057. IOP Publishing. DOI: https://doi.org/10.1088/1742-6596/1115/4/042057
19. Xiaohui, Shi, Weidong, Zeng, Yu, Sun et al. (2015) Microstructure-tensile properties correlation for the Ti–6Al–4V titanium
alloy. JMEPEG, 24(4), 1754–1762.
Suggested Citation
V.Yu. Bilous,
E.L. Vrzhizhevskyi,
R.V. Selin,
L.M. Radchenko,
S.L. Antoniuk (2026) Effect of vacuum annealing on the structure of high-temperature two-phase titanium (α+β)-alloy.
The Paton Welding J., 07, 26-33.
https://doi.org/10.37434/tpwj2026.07.05