Eng
Ukr
Print
2026 №02 (06) DOI of Article
10.37434/sem2026.02.07
2026 №02 (01)

Electrometallurgy Today 2026 #02
"Suchasna Elektrometallurgiya" (Electrometallurgy Today), 2026, 2, 57-64 pages

Influence of heat treatment on the structure of VT9 alloy

V.Yu. Bilous1, E.L. Vrzhizhevskyi1, R.V. Selin1, L.M. Radchenko1, S.L. Antoniuk2

1E.O. Paton Electric Welding Institute of the NAS of Ukraine 11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine. E-mail: belousvy@gmail.com
2SC «O.K.Antonov ANTK». 1 Mriya Str., 03062, Kyiv, Ukraine

Abstract
High-temperature titanium two-phase (α+β)-alloys can have high service properties when used in aircraft engines. In order to widen the scope of application or to restore the parts made from two-phase VT9 alloy, it is rational to consider the possibility of applying vacuum annealing for processing of the billets or parts after machining or welding. The influence of vacuum annealing at the temperature of 950 °C on the structure of sheets of VT9 titanium (α+β)-alloy was studied in the work. Sheets of VT9 titanium (α+β)-alloy 10 mm thick, were treated by vacuum annealing at the temperature of 950 °С for 1 h and were cooled with the furnace. Microstructure of the metal of samples of high-temperature two-phase titanium(α+β)-alloy VT9 in the initial condition is homogeneous, finely dispersed and consists of α-phase particles, with a thickness of 2…4 μm, and length of 2…20 μm. Microstructure of the metal of samples after vacuum annealing with further cooling with the furnace is homogeneous, and it consists of α-phase particles with a thickness of 2…6 μm and a length of up to 20 μm. An increase in the dimensions of the α-phase is noted, which is related to the process of its coagulation. Vacuum annealing at the temperature of 950 °С led to reduction of the number of dispersed particles in the metal structure and growth as a result of coagulation, during slow cooling of the α-phase particles. The quantity of the β-phase in the metal of the high-temperature titanium (α+β)-alloy VT9 decreases to 15...22 %. Such structural changes may lead to lowering of the alloy strength values and increase in the impact toughness values, which promotes an increase in service properties of parts from VT9 alloy. 19 Ref., 3 Tabl., 8 Fig.
Keywords: titanium alloy, two-phase (α+β)-alloys, microstructure, vacuum annealing, α-phase, β-phase

Received: .04.2026
Received in revised form: 11.05.2026
Accepted: 20.05.2026
Posted online: 27.05.2026

References

1. Firstov, S.O., Kulak, L.D., Kuzmenko, M.M., Shevchenko, O.M. (2018) Alloys of Ti–Al–Zr–Si system for high-temperature operation. Fizyko-Khimichna Mehanika Materialiv, 54(6), 30–35 [in Ukrainian]. http://jnas.nbuv.gov.ua/article/UJRN-0000958917
2. Shichen, Sun, Hongze, Fang, Yili, Li et al. (2023) Formation mechanism and effect on the mechanical properties of TiSi phase for Ti–5Al–5Mo–5Cr–3Nb–2Zr alloyed by silicon. J. of Alloys and Compounds, 938(25), 168510. DOI: https://doi.org/10.1016/j.jallcom.2022.168510
3. Gomez-Gallegos, A., Mandal, P., Gonzalez, D. et al. (2018) Studies on titanium alloys for aerospace application. Defect and Diffusion Forum, 385, 419–423. DOI: https://doi.org/10.4028/www.scientific.net/DDF.385.419
4. Williams, J.C., Boyer, R.R. (2020) Opportunities and issues in the application of titanium alloys for aerospace components. Metals, 10(6), 705. DOI: https://doi.org/10.3390/met10060705
5. Mantione, J., Garcia-Avila, M., Arnold, M. et al. (2020) Properties of novel high temperature titanium alloys for aerospace applications. In: Proc. of the MATEC Web of Conf., 321, 04006. DOI: https://doi.org/10.1051/matecconf/202032104006
6. Solonina, O.P., Glazunov, S.G. (1973) High-temperature titanium alloys. Moscow, Metallugiya.
7. Narushima, T., Sugizaki, Y. (2020) Recent activities of titanium research and development in Japan. In: Proc. of the MATEC Web of Conf., 321, 01004. DOI: https://doi.org/10.1051/matecconf/202032101004
8. Akhonin, S.V., Severin, A.Yu., Berezos, V.O. et al. (2021) Investigations of the quality of wrought semi-finished products of VT9 titanium alloy produced by electron beam melting. Suchasna Elektrometalurhiya, 4, 20–24. DOI: https://doi.org/10.37434/sem2021.04.03
9. Kaibyshev, O.A., Lutfullin, R.Ya., Salishchev, G.A. (1985) Microstructural changes in heat treatment and hot deformation of VT9 titanium alloy with lamellar microstructure. Fizika Metallov i Metallovedenie, 59(3), 578–583.
10. Skripalenko, M.M., Galkin, S.P., Karpov, B.V. et al. (2019) Forming features and properties of titanium alloy billets after radial-shear rolling. Materials, 12, 3179. DOI: https://doi.org/10.3390/ma12193179
11. Yadav, P., Saxena, K.K. (2020) Effect of heat-treatment on microstructure and mechanical properties of Ti alloys: An overview. Materials Today: Proceedings, 26, 2546–2557. DOI: https://doi.org/10.1016/j.matpr.2020.02.541
12. Berdin, V.K., Karavaeva, M.V., Nurieva, S.K. (2002) Influence of dispersity of lamellar microstructure on fragmentation of α-plates during hot deformation of VT9 titanium alloy. Materialovedenie, 12, 47–53.
13. Jian Zhou, Xia Li, Chaoyi Ding et al. (2025) Deformation response analysis of Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy under electromagnetic shock treatment via nanoindentation. Materials Characterization, Pt A, 229, 115551, DOI: https://doi.org/10.1016/j.matchar.2025.115551
14. Chai, Zaixian, Wang, William, Ren, Yong et al. (2024) Hot deformation behavior and microstructure evolution of TC11 dual-phase titanium alloy. Materials Science and Engineering: A, 898, 146331. DOI: https://doi.org/10.1016/j.msea.2024.146331
15. Akhonin, S.V., Pikulin, A.N., Klochai, V.V., Ryabtsev, A.D. (2019) Electron-beam surface treatment of titanium alloy ingots. Pt 1. Metallurgist, 63(1–2), 183–191. DOI: https://doi.org/10.1007/s11015-019-00808-9
16. Vodopyanova, O.V., Postylyakov, A.Yu., Shvarts, D.L. et al. (2022) Evaluation of VT6 and VT9 α+β titanium alloys spreading features during flat rolling. In: Proc. of the AIP Conf., 2456(1), 020039. DOI: https://doi.org/10.1063/5.0074585
17. Jia, X., Yang, Y., Di, R. (2025) Ti–6.5Al–3.5Mo–1.5Zr–0.3Si Alloy fabricated by laser melting deposition: Microstructure evolution and anisotropy. J. of Materials Engineering and Performance. DOI: https://doi:10.1007/s11665-025-12862-3
18. Pushilina, N.S., Kashkarov, E.B., Syrtanov, M.S. et al. (2018) Microstructure and properties of Ti–6.5Al–3.5Mo–1.5Zr– 0.3Si parts produced by electron beam melting. J. of Physics: Conf. Series, 1115(4), 042057. IOP Publishing. DOI: https://doi.org/10.1088/1742-6596/1115/4/042057
19. Xiaohui, Shi, Weidong, Zeng, Yu, Sun et al. (2015) Microstructure- tensile properties correlation for the Ti–6Al–4V titanium alloy. JMEPEG, 24(4), 1754–1762.
This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Suggested Citation

V.Yu. Bilous, E.L. Vrzhizhevskyi, R.V. Selin, L.M. Radchenko, S.L. Antoniuk (2026) Influence of heat treatment on the structure of VT9 alloy. Electrometallurgy Today, 02, 57-64. https://doi.org/10.37434/sem2026.02.07

Advertising in this issue: