The Paton Welding Journal, 2024, #9, 20-28 pages
Neutron shield materials based on boron carbide–tungsten multilayer composites
L. Chkhartishvili1,2, N. Barbakadze3, O. Tsagareishvili2, A. Mikeladze2, O. Lekashvili3, K. Kochiashvili3, R. Chedia2,3
1Georgian Technical University
77 Merab Kostava Ave., 0160, Tbilisi, Georgia. E-mail: levanchkhartishvili@gtu.ge
2F. Tavadze Metallurgy and Materials Science Institute
8b Elizbar Mindeli Str., 0186, Tbilisi, Georgia
3P. Melikishvili Institute of Physical and Organic Chemistry
31a Anna Politkovskaya Str., 0186, Tbilisi, Georgiae
Abstract
Nuclear power industry requires structural materials that effectively absorb neutron radiation. For this purpose, boron and
boron-rich compounds and, in particular, boron carbide B4C and its composites are widely used. Both theoretically and experimentally
it has been shown that one such promising class of materials is boron carbide compositions with tungsten B4C–W:
tungsten phase inclusions containing heavy W atoms provide effective attenuation of the secondary gamma-radiation that
accompany the absorption of primary neutrons by the boron 10B isotope atoms. In this work, the composites with multilayer
morphologies — W/B4C/W, W/B4C/W2B5, W2B5/B4C/W2B5, etc. — in which boron carbide layers alternate with metallic tungsten
and/or tungsten pentaboride ones, are produced and investigated. Surface metallization of boron carbide crystals or grains
with tungsten powder, plate or coating is done by SPS (Spark-Plasma Sintering) and also by standard thermal sintering. SEM
(Scanning Electron Microscopy) structural-morphological, XRD (X-Ray Diffraction) phase- and EDS (Energy Dispersive
Spectrometry) chemical-compositions analysis of the obtained samples establishes that transition layers of W2B5 are formed on
the B4C–W interfaces, which ensures component-layers strong bonding.
Keywords: boron carbide, tungsten, layered composite, metallization, thermal sintering, spark-plasma-sintering, radiation
shield
Received: 01.08.2024
Received in revised form: 04.09.2024
Accepted: 07.10.2024
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Suggested Citation
L. Chkhartishvili, N. Barbakadze, O. Tsagareishvili, A. Mikeladze, O. Lekashvili, K. Kochiashvili, R. Chedia (2024) Neutron shield materials based on boron carbide–tungsten multilayer composites.
The Paton Welding J., 09, 20-28.