Print
2026 №07 (02) DOI of Article
10.37434/tpwj2026.07.03
2026 №07 (04)

The Paton Welding Journal 2026 #07
The Paton Welding Journal, 2026, #7, 14-20 pages

Investigation of the evaporation behavior of alloying elements during electron beam melting of heat-resistant titanium alloys in the Ti–Al–Zr–Sn–Mo–Nb–Si alloy system

S.V. Akhonin, A.Yu. Severyn, O.G. Yerokhin, Yu.T. Ishchuk

E.O. Paton Electric Welding Institute of the NASU. 11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine. E-mail: akhonin.sv@gmail.com


Abstract
The thermodynamic and kinetic parameters of the metallic solution of the alloy of the Ti–Al–Zr–Sn–Mo–Nb–Si alloying system were determined, which made it possible to refine the model of the evaporation process of the elements of multicomponent alloys during electron beam melting cold hearth. It has been demonstrated that the mathematical model accurately describes the evaporation process of elements during the electron beam melting of high-temperature alloys of the Ti–Al–Zr–Sn–Mo–Nb–Si alloying system, as confirmed by full-scale experiments. The patterns of evaporation of alloy elements during electron beam melting were investigated, which make it possible to predict the final chemical composition of ingots and determine the melting parameters.
Keywords: electron beam melting, cold hearth, modeling, evaporation, high-temperature alloy, alloying elements, ingot

Received: 12.02.2026
Received in revised form: 08.04.2026
Accepted: 14.07.2026

References

1. Cormier, J. (2018) Ni- and Co-based superalloys and their coatings. Metals, 8, 1055. DOI: https://doi.org/10.3390/met8121055
2. Tajne, A., Gupta, T.V.K., Ramani, H., Joshi, Y. (2024) A critical review on the machinability aspects of nickel and cobalt based superalloys in turning operation used for aerospace applications. Advances in Materials and Processing Technologies, 10(2), 833–866. DOI: https://doi.org/10.1080/2374068X.2023.2185850
3. Liu, Z., Xin, S., Zhao, Y. (2023) Research progress on the creep resistance of high-temperature titanium alloys: A review. Metals, 13, 1975. DOI: https://doi.org/10.3390/met13121975
4. Casadebaigt, A., Hugues, J., Monceau, D. (2020) High temperature oxidation and embrittlement at 500...600 °C of Ti– 6Al–4V alloy fabricated by laser and electron beam melting. Corrosion Sci., 175, 108875. DOI: https://doi.org/10.1016/j.corsci.2020.108875
5. Firstov, S.A., Tkachenko, S.V., Kuz’menko, N.N. (2009) Titanium «irons» and titanium “steels”. Met. Sci. Heat Treat., 51, 12–18. DOI: https://doi.org/10.1007/s11041-009-9119-7
6. Firstov, S.O., Lugovskiy, Y.F., Kuzmenko, M.M. et al. (2023) Temperature dependencies of the mechanical properties of heat-resistant titanium alloys of the Ti–Si–X system under cyclic loading. Metallofiz. Noveishie Tekhnol., 45(3), 311‒327 [in Ukrainian]. DOI: https://doi.org/10.15407/mfint.45.03.0311
7. Shevchenko, O.M., Kulak, L.D., Kuzmenko, M.M. et al. (2023) The influence of the deformation and heat treatment on the structure and heat-resistance of Ti–Al–Zr–Si alloys. Materials Sci., 59(1), 40–48. DOI: https://doi.org/10.1007/s11003-023-00741-y
8. Akhonin, S.V., Severyn, A.Yu., Berezos, V.O. et al. (2024) Influence of deformation processing modes on the structure and mechanical properties of a high-temperature titanium alloy of the Ti–Al–Zr–Si–Mo–Nb–Sn system, Metallofiz. Noveishie Tekhnol., 46(7), 705–715. DOI: https://doi.org/10.15407/mfint.46.07.0705
9. Akhonin, S.V., Severin, A.Yu., Berezos, V.O. et al. (2022) Mathematical modeling of evaporation processes during the EBM of titanium aluminide-based alloys of the Ti–Al–Nb–Cr–Mo alloying system. Suchasna Elektrometalurhiya, 2, 10‒16 [in Ukrainian]. DOI: https://doi.org/10.37434/sem2022.02.02
10. Bellot, J.P., Duval, H., Ablitzer, D. (1996) Validity of the kinetic Langmuir’s law for the volatilization of metallic element in vacuum metallurgy. In: Proc. of Symp. оf Gas Interaction in Nonferrous Metals Processing, Anaheim, USA, Vol. 1, 109–124.
11. Bellot, J.P., Duval, H., Ritchie, M., Ablitzer, D. (1999) The use of mathematical models to determine parameters minimizing the volatilization losses in the electron beam melting process. In: Proc. of the 9th World Conf. on Titanium, St.-Petersburg, Russia, Vol. 1, 1442–1449.
12. Schiller, Z., Geising, U., Panzer, Z. (1980) Electron beam technology. Moscow, Energiya [in Russian].
13. Nakao, R., Fukumoto, S., Fuji, M. (1992) Evaporation of alloying elements and behavior of degassing reactions of high chromium steel in electron beam melting. ISIJ Inter., 32(5), 685–692. DOI: https://doi.org/10.2355/isijinternational.32.685
14. Jiahao Zhang, Tangqing Cao, Haoyue Ge et al. (2025) Investigation of element volatilization and impurity removal behavior in electron beam melting of VNbTaTi refractory high-entropy alloys. J. of Manufacturing Processes, 155, 185–197. DOI: https://doi.org/10.1016/j.jmapro.2025.10.020.
15. Akhonin, S.V., Trigub, N.P., Zamkov, V.N., Semiatin, S.L. (2003) Mathematical modeling of aluminum evaporation during electron-beam cold hearth melting of Ti–6Al–4V ingots. Metallurgy and Materials Transact., 4B, 447–454. DOI: https://doi.org/10.1007/s11663-003-0071-4
16. Honig, R.E. (1957) Vapor pressure data for the more common elements. RCA Review, 18, 195–204.
17. Mondal, B., Mukherjee, T., Finch, N.W. et al. (2023) Vapor pressure versus temperature relations of common elements. Materials, 16(1). DOI: https://doi.org/10.3390/ma16010050
18. Kostov, A., Živković, D. (2008) Thermodynamic analysis of alloys Ti–Al, Ti–V, Al–V and Ti–Al–V. J. of Alloys and Compounds, 460(1–2), 164–171, DOI: https://doi.org/10.1016/j.jallcom.2007.05.059
19. Akhonin, S.V., Berezos, V.O., Yerokhin, O.G. (2025) Production of high-strength titanium alloys by electron beam melting. Kyiv, PWI [in Ukrainian].
20. Akhonin, S., Pikulin, O., Berezos, V. at al. (2022) Determining the structure and properties of heat resistant titanium alloys VT3-1 and VT9 obtained by electron beam melting. Eastern-European J. of Enterprise Technologies, 5(12–119), 6–12. DOI: https://doi.org/10.15587/1729-4061.2022.265014/

Suggested Citation

S.V. Akhonin, A.Yu. Severyn, O.G. Yerokhin, Yu.T. Ishchuk (2026) Investigation of the evaporation behavior of alloying elements during electron beam melting of heat-resistant titanium alloys in the Ti–Al–Zr–Sn–Mo–Nb–Si alloy system. The Paton Welding J., 07, 14-20. https://doi.org/10.37434/tpwj2026.07.03