The Paton Welding Journal, 2026, #7, 14-20 pages
Investigation of the evaporation behavior of alloying elements during electron beam melting of heat-resistant titanium alloys in the Ti–Al–Zr–Sn–Mo–Nb–Si alloy system
S.V. Akhonin
, A.Yu. Severyn
, O.G. Yerokhin
, Yu.T. Ishchuk
E.O. Paton Electric Welding Institute of the NASU.
11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine.
E-mail: akhonin.sv@gmail.com
Abstract
The thermodynamic and kinetic parameters of the metallic solution of the alloy of the Ti–Al–Zr–Sn–Mo–Nb–Si alloying system
were determined, which made it possible to refine the model of the evaporation process of the elements of multicomponent alloys
during electron beam melting cold hearth. It has been demonstrated that the mathematical model accurately describes the evaporation
process of elements during the electron beam melting of high-temperature alloys of the Ti–Al–Zr–Sn–Mo–Nb–Si alloying system, as
confirmed by full-scale experiments. The patterns of evaporation of alloy elements during electron beam melting were investigated,
which make it possible to predict the final chemical composition of ingots and determine the melting parameters.
Keywords: electron beam melting, cold hearth, modeling, evaporation, high-temperature alloy, alloying elements, ingot
Received: 12.02.2026
Received in revised form: 08.04.2026
Accepted: 14.07.2026
References
1. Cormier, J. (2018) Ni- and Co-based superalloys and their
coatings. Metals, 8, 1055. DOI: https://doi.org/10.3390/met8121055
2. Tajne, A., Gupta, T.V.K., Ramani, H., Joshi, Y. (2024) A critical
review on the machinability aspects of nickel and cobalt
based superalloys in turning operation used for aerospace
applications. Advances in Materials and Processing Technologies,
10(2), 833–866. DOI: https://doi.org/10.1080/2374068X.2023.2185850
3. Liu, Z., Xin, S., Zhao, Y. (2023) Research progress on the
creep resistance of high-temperature titanium alloys: A review.
Metals, 13, 1975. DOI: https://doi.org/10.3390/met13121975
4. Casadebaigt, A., Hugues, J., Monceau, D. (2020) High temperature
oxidation and embrittlement at 500...600 °C of Ti–
6Al–4V alloy fabricated by laser and electron beam melting.
Corrosion Sci., 175, 108875. DOI: https://doi.org/10.1016/j.corsci.2020.108875
5. Firstov, S.A., Tkachenko, S.V., Kuz’menko, N.N. (2009) Titanium
«irons» and titanium “steels”. Met. Sci. Heat Treat.,
51, 12–18. DOI: https://doi.org/10.1007/s11041-009-9119-7
6. Firstov, S.O., Lugovskiy, Y.F., Kuzmenko, M.M. et al. (2023)
Temperature dependencies of the mechanical properties
of heat-resistant titanium alloys of the Ti–Si–X system under
cyclic loading. Metallofiz. Noveishie Tekhnol., 45(3),
311‒327 [in Ukrainian]. DOI: https://doi.org/10.15407/mfint.45.03.0311
7. Shevchenko, O.M., Kulak, L.D., Kuzmenko, M.M. et al.
(2023) The influence of the deformation and heat treatment
on the structure and heat-resistance of Ti–Al–Zr–Si alloys.
Materials Sci., 59(1), 40–48. DOI: https://doi.org/10.1007/s11003-023-00741-y
8. Akhonin, S.V., Severyn, A.Yu., Berezos, V.O. et al. (2024) Influence
of deformation processing modes on the structure and
mechanical properties of a high-temperature titanium alloy
of the Ti–Al–Zr–Si–Mo–Nb–Sn system, Metallofiz. Noveishie
Tekhnol., 46(7), 705–715. DOI: https://doi.org/10.15407/mfint.46.07.0705
9. Akhonin, S.V., Severin, A.Yu., Berezos, V.O. et al. (2022)
Mathematical modeling of evaporation processes during
the EBM of titanium aluminide-based alloys of the Ti–Al–Nb–Cr–Mo alloying system. Suchasna Elektrometalurhiya,
2, 10‒16 [in Ukrainian]. DOI: https://doi.org/10.37434/sem2022.02.02
10. Bellot, J.P., Duval, H., Ablitzer, D. (1996) Validity of the kinetic
Langmuir’s law for the volatilization of metallic element
in vacuum metallurgy. In: Proc. of Symp. оf Gas Interaction
in Nonferrous Metals Processing, Anaheim, USA, Vol. 1,
109–124.
11. Bellot, J.P., Duval, H., Ritchie, M., Ablitzer, D. (1999) The
use of mathematical models to determine parameters minimizing
the volatilization losses in the electron beam melting
process. In: Proc. of the 9th World Conf. on Titanium, St.-Petersburg,
Russia, Vol. 1, 1442–1449.
12. Schiller, Z., Geising, U., Panzer, Z. (1980) Electron beam
technology. Moscow, Energiya [in Russian].
13. Nakao, R., Fukumoto, S., Fuji, M. (1992) Evaporation of
alloying elements and behavior of degassing reactions of
high chromium steel in electron beam melting. ISIJ Inter.,
32(5), 685–692. DOI: https://doi.org/10.2355/isijinternational.32.685
14. Jiahao Zhang, Tangqing Cao, Haoyue Ge et al. (2025) Investigation
of element volatilization and impurity removal
behavior in electron beam melting of VNbTaTi refractory
high-entropy alloys. J. of Manufacturing Processes, 155,
185–197. DOI: https://doi.org/10.1016/j.jmapro.2025.10.020.
15. Akhonin, S.V., Trigub, N.P., Zamkov, V.N., Semiatin, S.L.
(2003) Mathematical modeling of aluminum evaporation
during electron-beam cold hearth melting of Ti–6Al–4V ingots.
Metallurgy and Materials Transact., 4B, 447–454. DOI:
https://doi.org/10.1007/s11663-003-0071-4
16. Honig, R.E. (1957) Vapor pressure data for the more common
elements. RCA Review, 18, 195–204.
17. Mondal, B., Mukherjee, T., Finch, N.W. et al. (2023) Vapor
pressure versus temperature relations of common elements.
Materials, 16(1). DOI: https://doi.org/10.3390/ma16010050
18. Kostov, A., Živković, D. (2008) Thermodynamic analysis of
alloys Ti–Al, Ti–V, Al–V and Ti–Al–V. J. of Alloys and Compounds,
460(1–2), 164–171, DOI: https://doi.org/10.1016/j.jallcom.2007.05.059
19. Akhonin, S.V., Berezos, V.O., Yerokhin, O.G. (2025) Production
of high-strength titanium alloys by electron beam melting.
Kyiv, PWI [in Ukrainian].
20. Akhonin, S., Pikulin, O., Berezos, V. at al. (2022) Determining
the structure and properties of heat resistant titanium alloys
VT3-1 and VT9 obtained by electron beam melting. Eastern-European J. of Enterprise Technologies, 5(12–119), 6–12.
DOI: https://doi.org/10.15587/1729-4061.2022.265014/
Suggested Citation
S.V. Akhonin,
A.Yu. Severyn,
O.G. Yerokhin,
Yu.T. Ishchuk (2026) Investigation of the evaporation behavior of alloying elements during electron beam melting of heat-resistant titanium alloys in the Ti–Al–Zr–Sn–Mo–Nb–Si alloy system.
The Paton Welding J., 07, 14-20.
https://doi.org/10.37434/tpwj2026.07.03