The Paton Welding Journal, 2021, #9, 2-8 pages
Classification of methods of modification and microalloying of deposited metal (Review)
A.A. Babinets and I.O. Ryabtsev
E.O. Paton Electric Welding Institute of the NASU.
11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine. E-mail: office@paton.kiev.ua
Abstract
A literature review of the main methods of modification and microalloying of deposited metal was made. It was shown
that, in contrast to the «microalloying» term, the «modification» term should mean not only a method of introducing
small additives of chemical elements or their compounds into the deposited metal but also various physical effects or
technological processes aimed at achieving the same goal – refinement of micro- and macrostructure of metal, cleaning
of grain boundaries and near-boundary zones, improving the complex of technological, mechanical and operational
properties of steels and alloys. Examples of such physical effects are application of vibrations to a product in the process
of surfacing; input of energy from a pulsed heat source; pulsed electrode or filler wire feed; application of sources
with modulation of welding current; external electromagnetic effect, etc. The classification of modification methods,
depending on the scheme of their implementation and impact on the properties of the deposited metal is given. The
main advantages and disadvantages of methods of introducing modifying and microalloying additives into the deposited
metal are shown. It was determined that from the considered methods of modification, the chemical method is the
simplest and the most rational, which implies introducing modifiers into the deposited metal directly through the charge
of flux-cored electrode wires. This method is technologically and economically simple and versatile, and can be used
with minor changes in electric arc, electroslag and plasma surfacing. 33 Ref., 1 Table, 3 Figures.
Keywords: arc surfacing, deposited metal, flux-cored wire, modification, microalloying, metal structure, service
properties
Received 21.07.2021
References
1. Manyak, N.A., Manyak, L.K. (2002) Influence of boron on structure and toughness of low-alloy steel. Metall i Lityo Ukrainy, 5-6, 23-25 [in Russian].
2. Lyakishev, N.P. (2000) Thesaurus on metallurgy. Moscow, Intermet Engineering [in Russian].
3. Bublikov, V.B. (2008) High-strength cast iron - 60 (Review). Litejnoe Proizvodstvo, 11, 2-8 [in Russian].
4. Goldshtejn, Ya.E., Mizin, V.G. (1986) Modification and microalloying of cast iron and steel. Moscow, Metallurgiya [in Russian].
5. Zadiranov, A.N., Kats, A.M. (2008) Theoretical principles of crystallization of metals and alloys. Moscow, MGIU [in Russian].
6. Boldyrev, A.M., Grigorash, V.V. (2011) Problems of microand nanomodification of welds in welding of building metal structures. Nanotekhnologii v Stroitelstve, 3(3), 42-52 [in Russian].
7. Zubenko, L.N. (2015) Applicaion of modifiers in composition of functional coatings. Tekhnologii i Materialy, 2, 20-23 [in Russian].
8. Sheksheev, M.A., Mikhailitsyn, S.V., Sychkov, A.B. et al. (2018) Examination of influence of ultradisperse particles of tungsten monocarbide on structure of deposited metal. VestnikYuzhno- Uralsky Gos. Un-ta, Series: Metallurgiya, 18(4), 128-136 [in Russian].
https://doi.org/10.14529/met1804149. Pulka, Ch.V., Shably, O.N., Senchishin, V.S., Sharyk, M.V., Gordan, G.N. (2012) Influence of vibration of parts on structure and properties of metal in surfacing. The Paton Welding J., 1, 23-25.
10. Lashchenko, G.I. (2016) Technological capabilities of vibration treatment of welded structures (Review). Ibid., 7, 26-31.
https://doi.org/10.15407/tpwj2016.07.0511. Razmyshlyaev, A.D., Ageeva, M.V. (2018) On mechanism of weld metal structure refinement in arc welding under action of magnetic fields (Review). Ibid., 3, 25-28.
https://doi.org/10.15407/tpwj2018.03.0512. Razmyshlyaev, A.D., Ageeva, M.V., Lavrova, E.V. (2019) Refinement of metal structure in arc surfacing under the effect of longitudinal magnetic field. Ibid., 2, 19-21.
https://doi.org/10.15407/tpwj2019.02.0213. Ryabtsev, I.A., Kuskov, Yu.M., Pereplyotchikov, E.F., Babinets, A.A. (2021) Surfacing. Control of base metal penetration and formation of deposited layers. Ed. by I.A.Ryabtsev. Kiev, Interservice [in Russian].
14. Kirian, V.I., Kajdalov, A.A., Novikova, D.P., Bogajchuk, I.L., Kesners, M. (2007) Improvement of welded joint structure under the impact of wideband ultrasonic vibrations during welding. The Paton Welding J., 2, 38-40.
15. Morozov, V.P. (2006) Peculiarities of process of primary structures formation of welds of different system aluminium alloys. Izv. Vuzov, Mashinostroenie, 9, 51-64 [in Russian].
16. Antonov, A.A., Artemiev, A.A., Sokolov, G.N. et al. (2016) Development of method of consumable electrode arc surfacing with filler wire. Sovremennye Problemy Teorii Mashin, 4(2), 99-101 [in Russian].
17. Boldyrev, A.M., Orlov, A.S., Gushchin, D.A. (2016) New technology for producing of granulated filler material with nanomodifying additives for arc welding of steels. Nanotekhnologii v Stroitelstve, 8(6), 124-143 [in Russian].
https://doi.org/10.15828/2075-8545-2016-8-6-124-14318. Gladky, P.V., Mikaelyan, G.S. (2015) Microalloying and modification of wear-resistant deposited metal. In: Surfacing. Technologies, materials, equipment. Kiev, PWI [in Russian].
19. Zusin, V.Ya. (2011) Investigation of modification of metal deposited by flux-cored wire with aluminium sheath. Vestnik Priazov. GTU. Series: Tekhnicheskie Nauki, 23, 180-183 [in Russian].
20. Shlepakov, V.N., Gavrilyuk, Yu.A., Naumejko, S.M. (2011) Development of flux-cored wire for arc welding of highstrength steel of bainite class. The Paton Welding J., 11, 15-18.
21. Fejnberg, L.I., Rybakov, A.A., Alimov, A.N., Rosert, R. (2007) Weld microalloying with titanuim and boron in multiarc welding of large diameter gas and oil pipes. Ibid., 5, 12-16.
22. Litvinenko-Arkov, V.B., Sokolov, G.N., Kyazymov, F.A. (2012) Structure and properties of heat-resistant metal, deposited by flux-cored wires with TiCN nanoparticles. Izv. Volgograd GTU, 9, 194-197 [in Russian].
23. Makarov, A.V., Kudryashov, A.E., Vladimirov, A.A., Titova, A.P. (2019) Application of deposited materials modifying with refractory components for restoration of rollers of billet continuous-casting machines. Vestnik Bryansk GTU, 8, 41- 48 [in Russian].
https://doi.org/10.30987/article_5d6cbe428ab026.7733549724. Golovko, V.V. (2018) Possibilities of nanomodification of dendrite structure of weld metal. The Paton Welding J., 8, 2-6.
https://doi.org/10.15407/tpwj2018.08.0125. Sokolov, G.N., Zorin, I.V., Artemiev, A.A. et al. (2014) Peculiarities of formation of structure and properties of deposited alloys under influence of refractory compound nanoparticles. Fizika i Khimiya Obrabotki Materialov, 2, 38-47 [in Russian].
26. Sokolov, G.N., Artemiev, A.A., Dubtsov, Yu.N. et al. (2018) Influence of nitrogen and titanium carbonitride particles on structure and properties of Fe-C-Cr-Ni-Mo system metal deposited by flux-cored wire. Omskij Nauchnyi Vestnik, 2, 15- 19 [in Russian].
https://doi.org/10.25206/1813-8225-2018-158-15-1927. Yakovlev, D.S., Shakhmatov, M.V. (2015) Microalloying of welded joints by flux-cored wire. Tekhnologii i Materialy, 2, 23-28 [in Russian].
28. Yakushin, B.F., Potapov, S.V., Kilyov, V.S. (2015) About direct modification of welding pool in submerged-arc welding. ESU, 12-5, 126-133 [in Russian].
29. Babu, N., Talari, M., Pan, D., Sun, Z., Wei, J., Sivaprasad, K. (2012) Microstructural characterization and grain refinement of AA6082 gas tungsten arc welds by scandium modified fillers. Materials Сhemistry and Physics, 137/2, 543-551.
https://doi.org/10.1016/j.matchemphys.2012.09.05630. Kuznetsov, V.D., Stepanov, D.V. (2015) Structure and properties of weld metal modified by nanooxides. The Paton Welding J., 11, 10-16.
https://doi.org/10.15407/tpwj2015.11.0131. Alyoshin, N.P., Grigorieva, M.V., Kobernik, N.V. et al. (2018) Modification of weld metal with tungsten carbide nanosized particles in twin-arc submerged-arc welding. Khimiya Vysokikh Energij, 52(5), 426-431 [in Russian].
https://doi.org/10.1134/S001814391805002832. Peremitko, V.V. (2014) Wear-resistant arc surfacing over the layer of alloying charge. The Paton Welding J., 8, 54-57.
https://doi.org/10.15407/tpwj2014.08.0933. Peremitko, V.V., Nosov, D.G. (2015) Optimization of modes of submerged arc surfacing over the layer of alloying charge of caterpillar machine running gear parts. Ibid.,
https://doi.org/10.15407/tpwj2015.06.10
Suggested Citation
A.A. Babinets and I.O. Ryabtsev (2021) Classification of methods of modification and microalloying of deposited metal (Review).
The Paton Welding J., 09, 2-8.