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2021 №09 (06) DOI of Article
2021 №09 (08)

The Paton Welding Journal 2021 #09
TPWJ, 2021, #9, 44-48 pages

Chemical equilibrium in Fe–O–H system at high temperatures

M.M. Gasik1 and M.I. Gasik2
1Aalto University 00076, Aalto, Espoo, Finland. E-mail: michael.gasik@aalto.fi
2National Metallurgical Academy of Ukraine 4 Gagarin Prosp., 49000, Dnipro, Ukraine

The issue of thermodynamic equilibrium in Fe–O–H system at the temperature of steel-making processes (1600 °C) was considered. The historical data array, features of experiments on obtaining them and their drawbacks were analyzed. A new more correct calculation of hydrogen and oxygen concentration in liquid iron and in the gas phase was performed. New coefficients of activity were calculated, proceeding from precise thermodynamic principles, unlike the earlier used artificial models based on interaction parameters. 19 Ref., 6 Figures.
Keywords: thermodynamics; iron, hydrogen; oxygen; solutions; activity; equilibrium

Received 26.04.2021


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