The Paton Welding Journal, 2020, #2, 2-8 pages
Formation of the structure and mechanical properties of joints of tialnb intermetallic alloy in diffusion welding
N.V. Piskun, Yu.V. Falchenko, L.V. Petrushinets, A.I. Ustinov, T.V. Melnichenko and I.I. Statkevich
E.O. Paton Electric Welding Institute of the NAS of Ukraine
11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine. E-mail: office@paton.kiev.ua
Abstract
The impact of technological measures in vacuum diffusion welding on formation of the structure and mechanical properties
of joints of TiAlNb intermetallic alloy was studied in the work. It is shown that welding of intermetallic alloy
by the method of vacuum diffusion welding at temperature Tw = 1050 °C, pressure Pw = 10 MPa, for 20 min does not
ensure producing sound joints. After welding, the joint line is visible in the butt, along which there is a considerable
number of defects in the form of pore lines. Increase of welding parameters up to temperature Tw = 1200 °C, pressure
Pw = 30 MPa, welding time of 30 min, as well as application of a ductile interlayer from NbTi alloy 1 mm thick allows
improving the conditions of welded joint formation and greatly reducing the number of defects in the butt joint. During
welding, common grains and diffusion zone 25–35 μm thick form between the interlayer material and the intermetallic
alloy. Application of nanolayered interlayer of Al−Ti system of the total thickness of 25 μm in welding of TiAlNb intermetallic
alloy, combined with cyclic loading in the form of 3 cycles of loading-unloading leads to a change of the nature
of the structure in the joint zone. In the microstructures of welded joints obtained by optical metallography, the joint line
is not visible. Application of electron microscopy allows detecting in the butt joint a diffusion zone 15 to 20 μm thick,
close by its chemical composition to that of the intermetallic alloy. Investigation of the compressive strength of welded
joints demonstrated that the average strength of joints of TiAlNb intermetallic alloy, produced using an interlayer from
NbTi alloy, is equal to 988.2 MPa, and application of a nanolayered interlayer of Al–Ti system in welding allows increasing
the average strength of the samples up to 1279.8 MPa. 16 Ref., 2 Tables, 8 Figures.
Keywords: TiAlNb intermetallic alloy, diffusion welding, interlayers, joint microstructure
Received 20.12.2019
References
1. Bochvar, G.A., Salenkov, V.A. (2004) Investigation of alloys based on titanium aluminide with orthorhombic structure. Tekhnologiya Lyogkikh Splavov, 4, 44-46 [in Russian].
2. Clemens H., Mayer S. (2013) Design, Processing, Microstructure, Properties, and Applications of Advanced Intermetallic TiAl Alloys. Advanced Engineering Materials, 4. 191-215.
https://doi.org/10.1002/adem.2012002313. Huber D., Werner R., Clemens H., Stockinger M. (2015) Influence of process parameter variation during thermo-mechanical processing of an intermetallic β-stabilized γ-TiAl based alloy. Materials Characterization, 109, 116-121.
https://doi.org/10.1016/j.matchar.2015.09.0214. Godor F., Werner R., Lindemann J., Clemens H. (2015) Characterization of the high temperature deformation behavior of two intermetallic TiAl-Mo. Materials Science and Engineering: A, 648, 208-216.
https://doi.org/10.1016/j.msea.2015.09.0775. Appel F. Paul J.D.H., Oering M. (2011) Gamma Titanium Aluminide Alloys: Science and Technology. Weinheim, WILEY-VCH.
https://doi.org/10.1002/97835276362046. Huang Z.W., Cong T. (2010) Microstructural instability and embrittlement behaviour of an Al-lean, high-Nb γ-TiAl-based alloy subjected to a long-term thermal exposure in air. Intermetallics, 18, 161-172.
https://doi.org/10.1016/j.intermet.2009.07.0077. Schwaighofer E., Clemens H., Mayer S. et al. (2014) Microstructural design and mechanical properties of a cast and heattreated intermetallic multi-phase γ-TiAl based alloy. Ibid, 44, 128-140.
https://doi.org/10.1016/j.intermet.2013.09.0108. Cam G., Ipekoglu G., Bohm K.-H., Kocak M. (2006) Investigation into the microstructure and mechanical properties of diffusion bonded TiAl alloys. J. of Materials Science, 16, 5273-5282.
https://doi.org/10.1007/s10853-006-0292-49. Lei Zhu, Xiang-Yi Xue, Bin Tang et al. (2016) The Influence of Surface Roughness on Diffusion Bonding of High Nb Containing TiAl Alloy. Proceedings of the 2nd Annual International Conference on Advanced Material Engineering (AME 2016), 635-643.
https://doi.org/10.2991/ame-16.2016.10610. Kun Zhao, Yong Liu, Lan Huang et al. (2016) Diffusion bonding of Ti-45Al-7Nb-0.3W alloy by spark plasma sintering. J. of Materials Processing Technology, 230, 272-279.
https://doi.org/10.1016/j.jmatprotec.2015.11.03011. Bin Tang, Xian Sheng Qi, Hong Chao Kou et al. (2016) Recrystallization Behavior at Diffusion Bonding Interface of High Nb Containing TiAl Alloy. Advanced Engineering Materials, 4, 657-664.
https://doi.org/10.1002/adem.20150045712. Cao J., Feng J.C., Li Z.R. (2007) Effect of reaction heat on reactive joining of TiAl intermetallics using Ti-Al-C interlayers. Scripta Materialia, 5, 421-424.
https://doi.org/10.1016/j.scriptamat.2007.04.04813. Ustinov A.I., Falchenko Yu.V., Ishchenko A.Ya. et al. (2008) Diffusion welding of γ-TiAl based alloys through nano-layered foil of Ti/Al system. Intermetallics, 8, 1043-1045.
https://doi.org/10.1016/j.intermet.2008.05.00214. Pflumma R., Donchev A., Mayer S. et al. (2014) High-temperature oxidation behavior of multi-phase Mo-containing γ-TiAl-based alloys. Ibid, 53, 45-55.
https://doi.org/10.1016/j.intermet.2014.04.01015. Kartavykh A.V., Asnis E.A., Piskun N.V. et al. (2015) Microstructure and mechanical properties control of c-TiAl(Nb, Cr, Zr) intermetallic alloy by induction float zone processing. J. of Alloy and Compounds, 643, 182-166.
https://doi.org/10.1016/j.jallcom.2014.12.21016. Kartavykh A.V., Asnis E.A., Piskun N.V. et al. (2017) Room-temperature tensile properties of float-zone processed β-stabilized γ-TiAl(Nb,Cr,Zr) intermetallic. J. Materials Letters, 188, 88-91.
https://doi.org/10.1016/j.matlet.2016.10.103
Suggested Citation
N.V. Piskun, Yu.V. Falchenko, L.V. Petrushinets, A.I. Ustinov, T.V. Melnichenko and I.I. Statkevich (2020) Formation of the structure and mechanical properties of joints of tialnb intermetallic alloy in diffusion welding.
The Paton Welding J., 02, 2-8.