Eng
Ukr
Rus
Print

2023 №02 (02) DOI of Article
10.37434/sem2023.02.03
2023 №02 (04)

Electrometallurgy Today 2023 #02
Electrometallurgy Today (Sovremennaya Elektrometallurgiya), 2023, #2, 23-29 pages

Structure and biomedical characteristics of calcium-phosphate materials, produced by electron beam deposition

L.A. Krushinska1, Ya.A. Stelmakh1, І.M. Аndrusyshyna2

1E.O. Paton Electric Welding Institute of the NAS of Ukraine. 11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine. E-mail: office@paton.kiev.ua
2Kundiev Institute of Occupational Medicine of the NAMS of Ukraine. 75 Saksaganskogo Str., 01033, Kyiv, Ukraine. E-mail: andrusyshyna.in@gmail.com

Abstract
The method of electron beam deposition on titanium substrates was used to produce multiphase nanosized calcium phosphate materials with Ca/P atomic ratio lower than the stoichiometric one. The influence of substrate temperature on the elemental and phase composition of calcium-phosphate materials is considered. It is shown that the structure of the components of such materials can be controlled by technological means, using deposition temperature. Calcium titanates, forming during deposition, are promising for designing multilayer composite materials or prosthesis products. Results of studying resorption of calcium-phosphate materials in biological and model solutions with different pH are presented. On the whole, the formed calcium-phosphate materials belong to bioresorbable ones, and they can be used to improve the biocompatibility with bone tissue. 13 Ref., 2 Tables, 6 Figures.
Keywords: EB PVD, structure, bioresorption, calcium-phosphate materials, calcium triphosphate, titanium

Received 14.02.2023

References

1. Epple, M. (2007) Biomaterials and biomineralization. Ed. by V.F. Pichugin et al. Tomsk, Veter [in Russian].
2. Ratner, B.D., Hoffman, A.S., Schoen, F.J., Lemons, J.E. (2004) Biomaterials science: An introduction to materials in medicine. 2nd Ed. Elsevier Inc.
3. Jarho, M., Kay, J., Gumaer, K., Doremus, R., Drobeck, H. (1977) Tissue, cellular and subcellular events at a bone-ceramic hydroxylapatite interface. J. Bioengineering, 1, 79-92.
4. Krushinskaya, L.A., Stelmakh, Ya.A. (2019) Composite material based on porous titanium, produced by vapour-phase deposition. Suchasna Elektrometal., 4, 51-57 [in Russian]. https://doi.org/10.15407/sem2019.04.08
5. DSTU EN ISO 11885:2019: Determination of 33 elements by atomic emission spectrometry method with inductively coupled plasma in water. Kyiv, Derzhspozhyvstandart Ukrainy [in Ukrainian].
6. Antomonov, M.Yu. (2006) Mathematical processing and analysis of medicobiological data. Kyiv, MDK [in Russian].
7. Veresov, A.G., Putlyaev, V.I., Tretiyakov, Yu.D. (2004) Chemistry of inorganic biomaterials based on calcium phosphate. J. of the D.I. Mendeleev Russian Chemical Society, 48, 52-64 [in Russian].
8. Gnezdenkov, S.V., Sharkeev, Yu.P., Sinebryukhov, S.L. et al. (2012) Functional coatings for implants. Pacific Medical J., 1, 12-19.
9. Putljaev, V.I. (2004) Modern bio-ceramic materials. Sorosovskij Obrazovatelnyj Zhurnal, 8(1), 44-50.
10. Shashkina, G.A., Ivanov, M.B., Legostaeva, E.V. et al. (2004) Bioceramic coatings with high calcium content for medicine. Fizicheskaya Mezomekhanika, 7(2), 123-126 [in Russian].
11. Zhao, Z., Wen, S. (2007) Direct preparation of CaTi4(PO4)6 coatings on the surface of titanium substrate by micro arc oxidation. J. Mater Sci. Mater. Med., 18(12), 2275-2281. https://doi.org/10.1007/s10856-007-3115-5
12. Kamyshnikov, V.S. (2009) Clinical laboratory tests from A to Z and their diagnostic meaning. 4th Ed. Moscow, MEDpressinform [in Russian].
13. Xiao Bai, Stefan Sandukas, Mark, R. et al. (2009) Deposition and investigation of functionally graded calcium phosphate coating on titanium. Acta Biomaterialia, 5, 3567-6572. https://doi.org/10.1016/j.actbio.2009.05.013

Advertising in this issue: