The Paton Welding Journal, 2023, #6, 24-31 pages
Properties of coatings produced by hvof-spraying of composite powders based on amorphized FeMoNiCrB alloy
N.V. Vigilanska1, C. Senderowski2, K.V. Yantsevych1, O.I. Dukhota3
1E.O. Paton Electric Welding Institute of the NASU..
11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine. E-mail: pewinataliya@gmail.com
2Warsaw University of Technology, Pl. Politechniki 1, 00661, Warsaw, Poland
3National Aviation University, 1, Lubomir Husar Ave, 03058 Kyiv, Ukraine
Abstract
Applying the method of HVOF-spraying with the use of mechanically-alloyed powders based on the amorphized FeMoNiCrB
alloy with the additions of (Ti, Cr)C and FeTiO3 compounds, the coatings with amorphous crystalline heterophase structure were
produced. The coatings of FeMoNiCrB‒(Ti, Cr)C and FeMoNiCrB‒FeTiO3 systems have a dense fine-grained structure with a
porosity of 2.4 and 1.2 % and a hardness of 5510 ± 250 and 4410 ± 190 MPa, respectively. The study of corrosion resistance and
resistance to fretting corrosion of the developed coatings was conducted. It is shown that the use of composite powders based on
FeMoNiCrB alloy with the addition of (Ti, Cr)C and FeTiO3 compounds as spraying materials allows increasing the protective
properties of the coatings compared to the coating of FeMoNiCrB alloy. It was found, that in the case of producing composite
FeMoNiCrB‒(Ti, Cr)C and FeMoNiCrB‒FeTiO3 coatings on the steel base St3, the corrosion resistance of the specimens in
the solutions of 3% NаСl, 10% Н2SО4 and 10% КОН is increased by 7.3, 9; 3.9, 5.3 and 9.5, 9.7 times, respectively. FeMoNi-CrB‒(Ti, Cr)C and FeMoNiCrB‒FeTiO3 coatings have a fairly high resistance to fretting corrosion, which is 4.6 and 5.8 times
higher than the resistance of titanium ОТ4-1 alloy. The obtained results indicate the prospect of using HVOF-spraying of the
developed FeMoNiCrB-(Ti, Cr)C and FeMoNiCrB-FeTiO3 coatings to strengthen and restore surfaces operating in aggressive
environments and those subjected to fretting corrosion. 26 Ref., 6 Tabl., 4 Fig.
Keywords: HVOF-spraying, amorphous phase, amorphous iron-based alloy, composition coating, corrosion resistance, fretting
corrosion
Received: 03.05.2023
Accepted: 17.07.2023
References
1. Stachurski, Z.H. (2011) On Structure and Properties of Amorphous Materials. Materials, 4(9), 1564-1598.
https://doi.org/10.3390/ma40915642. Hashimoto, K. (2011) What we have learned from studies on chemical properties of amorphous alloys. Applied Surface Science, 257(19), 8141-8150.
https://doi.org/10.1016/j.apsusc.2010.12.1423. An, Y., Hou, G., Chen, J. et al. (2014) Microstructure and tribological properties of iron-based metallic glass coatings prepared by atmospheric plasma spraying. Vacuum, 107, 132-140.
https://doi.org/10.1016/j.vacuum.2014.04.0214. Yugeswaran, S., Kobayashi, A. (2014) Metallic glass coatings fabricated by gas tunnel type plasma spraying. Vacuum, 110, 177-182.
https://doi.org/10.1016/j.vacuum.2014.04.0165. Li, G., Gan, Y., Liu, C. et al. (2020) Corrosion and Wear Resistance of Fe-Based Amorphous Coatings. Coatings, 10(1), 73.
https://doi.org/10.3390/coatings100100736. Lin, J., Wang, Z., Lin, P. et al. (2014) Microstructure and cavitation erosion behavior of FeNiCrBSiNbW coating prepared by twin wires arc spraying process. Surface and Coatings Technology, 240, 432-436.
https://doi.org/10.1016/j.surfcoat.2013.12.0717. АрArtemchuk, V.V. (2011) Structure and properties of Fe-based amorphous detonation coatings. Visnyk Dnipr. Nats. Un-tu Zalizn. Transportu, 36, 39-44.
https://doi.org/10.15802/stp2011/87078. Borysov, Yu.S., Borysova, A.L., Tsymbalista, T.V. et al. (2021) Producing and properties of detonation coatings based on FeMoNiCrB amorphizing alloy with addition of strengthening phases. The Paton Welding J., 12, 29-35.
https://doi.org/10.37434/as2021.12.059. Ma, H.R., Chen, X.Y., Li, J.W. et al. (2016) Fe-based amorphous coating with high corrosion and wear resistance. Surface Engineering, 33(1), 56-62.
https://doi.org/10.1080/02670844.2016.117671810. Wang, G., Huang, Z., Xiao, P., Zhu, X. (2016) Spraying of Fe-based amorphous coating with high corrosion resistance by HVAF. Journal of Manufacturing Processes, 22, 34-38.
https://doi.org/10.1016/j.jmapro.2016.01.00911. Liu, L., Zhang, C. (2014) Fe-based amorphous coatings: Structures and properties. Thin Solid Films, 561, 70-86.
https://doi.org/10.1016/j.tsf.2013.08.02912. Yugeswaran, S., Kobayashi, A., Suresh, K., Subramanian, B. (2013) Characterization of gas tunnel type plasma sprayed TiN reinforced Fe-based metallic glass coatings. Journal of Alloys and Compounds, 551, 168-175.
https://doi.org/10.1016/j.jallcom.2012.09.11113. Yoon, S., Kim, J., Kim, B.D., Lee, C. (2010) Tribological behavior of B4C reinforced Fe-base bulk metallic glass composite coating. Surface and Coatings Technology, 205(7), 1962-1968.
https://doi.org/10.1016/j.surfcoat.2010.08.07814. Terajima, T., Takeuchi, F., Nakata, K. et al. (2010) Composite coating containing WC/12Co cermet and Fe-based metallic glass deposited by high-velocity oxygen fuel spraying. Journal of Alloys and Compounds, 504, S288-S291.
https://doi.org/10.1016/j.jallcom.2010.03.20915. Chu, Z., Yang, Y., Chen, X. et al. (2016) Characterization and tribology performance of Fe-based metallic glassy composite coatings fabricated by gas multiple-tunnel plasma spraying. Surface and Coatings Technology, 292, 44-48.
https://doi.org/10.1016/j.surfcoat.2016.03.02416. Zhou, Z., Han, F.-X., Yao, H.-H. et al. (2021) Novel Fe-Based Amorphous Composite Coating with a Unique Interfacial Layer Improving Thermal Barrier Application. ACS Applied Materials & Interfaces, 13(19), 23057-23066.
https://doi.org/10.1021/acsami.0c2286817. Yasir, M., Zhang, C., Wang, W. et al. (2015) Wear behaviors of Fe-based amorphous composite coatings reinforced by Al2O3 particles in air and in NaCl solution. Materials & Design, 88, 207-213.
https://doi.org/10.1016/j.matdes.2015.08.14218. Umanskii, A.P., Konoval, V.P., Panasyuk, A.D. et al. (2007) Plasma coatings of (TiCrC)-(FeCr) composite powder alloys: Structure and properties. Powder Metallurgy and Metal Ceramics, 46(3-4), 133-138.
https://doi.org/10.1007/s11106-007-0022-819. Abdou, M.I., Ayad, M.I., Diab, A.S.M. et al. (2017) Influence of surface modified ilmenite/melamine formaldehyde composite on the anti-corrosion and mechanical properties of conventional polyamine cured epoxy for internal coating of gas and oil transmission pipelines. Progress in Organic Coatings, 113, 1-14.
https://doi.org/10.1016/j.porgcoat.2017.08.00320. Surzhenkov, A., Antonov, M., Goljandin, D. et al. (2013) Sliding wear of TiC-NiMo and Cr3C2-Ni cermet particles reinforced FeCrSiB matrix HVOF sprayed coatings. Estonian Journal of Engineering, 19(3), 203-211.
https://doi.org/10.3176/eng.2013.3.0321. Borysov, Yu.S., Borysova, A.L., Burlachenko, O.M. (2021) Composite powders based on FeMoNiCrB amorphizing alloy with additives of refractory compounds for thermal spraying of coatings. The Paton Welding J., 11, 38-47.
https://doi.org/10.37434/tpwj2021.11.0722. Borysov, Yu.S., Vihilianska, N.V., Demianov, I.A. et al. (2022) Studies of coatings produced by high-velocity oxyfuel spraying using cermet powder based on FeMoNiCrB amorphizing alloy. The Paton Welding J., 2, 33-36.
https://doi.org/10.37434/tpwj2022.02.0523. Pokhmurskyi, V.I., Khoma, M.S. (2008) Corrosion fatigue of metals and alloys. Lviv, SPOLOM [in Ukrainian].
24. талів від корозії. Донецьк, Східний видавничий дім. Alimov, V.I., Duryagina, Z.A. (2012) Corrosion and corrosion protection of metals. Donetsk, Skhidnyi Vydavnichyi Dim [in Ukrainian].
25. Tomashov, N.D., Chernova, G.P., Kornienko, L.P. (1982) Corrosion resistance of titanium in technological environments of chemical industry. Moscow, NII Tekhim [in Russian].
26. Hariharasakthisudhan, P., Rajan, B.S., Sathickbasha, K. (2020) Inspiration of reinforcements, manufacturing methods, and microstructural changes on wear behavior of metal matrix composites - a recent review. Materials Research Express, 7(1), 012006.
https://doi.org/10.1088/2053-1591/ab6918
Suggested Citation
N.V. Vigilanska, C. Senderowski, K.V. Yantsevych, O.I. Dukhota (2023) Properties of coatings produced by hvof-spraying of composite powders based on amorphized FeMoNiCrB alloy.
The Paton Welding J., 06, 24-31.