The Paton Welding Journal, 2021, #12, 29-35 pages
Producing and properties of detonation coatings based on FeMoNiCrB amorphizing alloy with addition of strengthening phases
Yu.S. Borysov, A.L. Borysova, T.V. Tsymbalista, A.I. Kildiy, K.V. Yantsevych, Z.G. Ipatova
E.O. Paton Electric Welding Institute of the NASU.
11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine. E-mail: borisov@paton.kiev.ua
Abstract
The structure and properties of amorphizing composite detonation coatings based on FeMoNiCrB alloy were studied.
FeMoNiCrB + ZrB2, FeMoNiCrB + (Ti, Cr)C, FeMoNiCrB + FeTiO3 composite powders were used for coatings deposition,
which were produced from a mixture of the composition powders by mechanical alloying. It is found that as a result of detonation
spraying of all the powder compositions, the formed coatings have dense, lamellar, multiphase structure. The coating
composition includes Fe(Ni, Cr) solid solutions, Mo2FeB2 and Fe2B borides, dispersed inclusions of alloying additives (ZrB2,
(Ti, Cr)C, FeTiO3) and oxides (ZrO2 and FeCr2O4 or Fe2O3, or Fe3O4), as well as an amorphous phase, the amount of which
in the coating structure has increased, as a result of the detonation spraying process. The values of microhardness, corrosion
resistance, fatigue life and wear resistance of the composite detonation coatings are given.
Keywords: detonation spraying, composite powders, amorphizing iron alloy, zirconium boride, titanium-chromium carbide,
iron titanate, coating, corrosion resistance, wear resistance
Received 12.10.2021
Accepted: 24.12.2021
References
1. Suzuki, K., Fujimori, H., Hashimoto, K. (1987) Amorphous
metals. Moscow, Metallurgiya [in Russian].
2. Lyuborskij, F.E. (1987) Amorphous metal alloys. Moscow,
Metallurgiya [in Russian].
3. Kunitskij, Yu.A., Borisov, Yu.S., Korzhik, V.N. (1989) Noncrystalline
metal materials and coatings in engineering. Kiev,
Tekhnika [in Russian].
4. Borisov, Yu.S., Borisova, A.L., Burlachenko, O.M. (2021) Composite powders based on FeMoNiCrB amorphizing alloy with additives of refractory compounds for thermal spraying of coatings. The Paton Welding J., 11, 44-53.
https://doi.org/10.37434/as2021.11.085. (2007) GOST R 9.905–2007: Unified system of corrosion and
ageing protection. Corrosion test methods. General requirements.
Moscow, Izd-vo Standartov [in Russian].
6. Zhuk, N.P. (2006) Lectures on theory of corrosion and metal
protection. Moscow, Alyans [in Russian].
7. Semenova, I.V., Florionovich, G.M., Khoroshilov, A.V.
(2002) Corrosion and protection from corrosion. Moscow,
Fizmatlit [in Russian].
8. (1981) GOST 23.208–79: Ensuring of wear resistance of
products. Wear resistance testing of materials by friction
against loosely fixed abrasive particles. Moscow, Izd-vo
Standartov [in Russian].
9. Grigorenko, G.M., Borisova, A.L., Adeeva, A.I., Sladkova,
V.N. (1995) Application of method of quantitative X-ray
structure analysis at investigation of phase composition of
thermal coatings. Problemy Spets. Elektrometallurgii, 2, 63–
71 [in Russian].
10. (1999) GOST 9.909–86: Metals, alloys, metal and nonmetal
inorganic coatings. Moscow, Izd-vo Standartov [in Russian].
11. Gerts, I. (1979) Passivation of wrought nickel in sulfuric acid.
Zashchita Metallov, 15(1), 29–33 [in Russian].
12. Tulskyi, G.G., Artemenko, V.M., Deribo, S.G. (2019) Theoretical
electrochemistry. Kharkiv, KhPI [in Ukrainian].
Suggested Citation
Yu.S. Borysov, A.L. Borysova, T.V. Tsymbalista, A.I. Kildiy, K.V. Yantsevych, Z.G. Ipatova (2021) Producing and properties of detonation coatings based on FeMoNiCrB amorphizing alloy with addition of strengthening phases.
The Paton Welding J., 12, 29-35.