Electrometallurgy Today (Sovremennaya Elektrometallurgiya), 2024, #2, 5-12 pages
Development of the technology of ferronickel production in Ukraine
D. Shevchenko1, S. Prikhodko1, A. Nadtochii2, V. Shutov3, A. Ovcharuk2
1Pobuzky Ferronickel Plant. 12 Promyslova Str., Pobuzke village, Golovanivsky district,
Kirovohrad region, 26555, Ukraine. E-mail: office@pfk.com.ua
2Ukrainian State University of Science and Technology.
4 Nauky Prosp., 49600, Dnipro, Ukraine. E-mail: tehnosplavy.dnepr@gmail.com
3National Technical University «Dnipro Polytechnic».
19 Dmytro Yavornytskyi Prosp., 49005, Dnipro, Ukraine
Abstract
The paper summarizes the results of numerous works performed by the employees of the Pobuzky Ferronickel Plant,
the Department of Electrometallurgy of the USU of Science and Technology (Dnipro), RPC «Technosplavy» under the
leadership of Mykhailo Hasyk, academician of NASU. A technology of low iron recovery has been implemented at the
plant, which allows producing high-percentage black ferronickel, containing 30…50 % Ni, and almost hundredth fractions
of carbon and silicon, directly in electric furnaces. The thermodynamic features of off-kiln ladle desulfurization
of ferronickel with soda are considered. A complex technology has been developed and implemented, which involves
mixing crude ferronickel produced in one furnace with a reduced silicon and carbon content (up to 0.01 %) and a high
nickel content (over 50 %) with an alloy from another furnace with a low nickel concentration (10…17 %) and a high
concentration of silicon and carbon, which are so necessary for desulfurization with soda in a ladle. The developed and
proposed technological schemes for the enrichment of electric furnace slags using the «wet» technology and refining
slags using the «dry» technology make it possible to recycle about 1,200 tons of nickel per year, or to extract 31.6 %
and 94.65 % of nickel from the slags, respectively. 19 Ref., 4 Tabl., 3 Fig.
Keywords: Pobuzki Ferronickel Plant, cinder, black ferronickel, ladle desulfurization, refining, slag enrichment
Received: 07.04.2024
Received in revised form: 21.04.2024
Accepted: 03.06.2024
References
1. Gasyk, M.I., Lyakishev, M.P. (2009) Physics-chemistry and technology of ferroalloys: Manual. 3rd Ed. Dnipro, Systemni Tekhnologii [in Ukrainian].
2. Sokolov, K.D., Kapran, I.I., Likhachev, V.F. (2000) Examination of lining operation of ore-thermal furnace in melting of ferronickel. Metallurgicheskaya i Gornorudnaya Promyshlennost, 6, 32-35 [in Russian].
3. Novikov, N.V., Kapran, I.I., Sokolov, K.D. et al. (2006) Petrographic examinations of interaction of periclase-chromium lining of ore-smelting furnace with melt of ferronickel and furnace slag. Metallurgicheskaya i Gornorudnaya Promyshlennost, 2, 27-30 in Russian].
4. Novikov, N.V., Sokolov, K.D., Kapran, I.I., Ovcharuk, A.N. (2005) Material balance of process of ferronickel production. Metallurgicheskaya i Gornorudnaya Promyshlennost, 4 , 20-24 [in Russian].
5. Novikov, N.V., Sokolov, K.D., Kapran, I.I., Ovcharuk, A.N. (2005) Examination of chemical, mineralogical and phase composition of nickel ore for ferronickel melting. Metallurgicheskaya i Gornorudnaya Promyshlennost, 5 , 19-22 [in Russian].
6. Bespalov, O.L., Sokolov, K.D., Prikhodko, S.V. et al. (2017) State-of-the-art and prospects of improvement of ferronickel production technology. In: Current problems of development of metallurgical science and education, 204-211 [in Russian].
7. Gasyk, M.I., Zaporozhets, B.O., Novykov, M.V. et al. (2011) Method of melting of roughing ferronickel with optimal silicon content. Pat. 62847, Ukraine, Int. Cl. С 22 В 23/00 [in Ukrainian].
8. Gasyk, M.I., Zaporozhets, B.O., Kapran, I.I. et al. (2004) Start section of self-sintering electrode. Pat. 2852, Int. Cl. H05B7/09 C21B11/10 C01B31/02 [in Ukrainian].
9. Gasyk, M.I., Kapran, I.I., Kashkul, V.V. et al. (2004) Method of initial sintering of self-sintering electrode. Pat. 2854, Ukraine. Int. Cl. C01B31/02 H05B7/09 [in Ukrainian].
10. Bespalov, O.L., Prykhodko, S.V., Danov, O.V. et al. (2016) Reducing mixture for electrothermal ferronickel production. Pat. 109001, Ukraine. Int. Cl. C22 B 4/06 [in Ukrainian].
11. Bespalov, O.L., Mashiyanov, V.G., Solokha, V.K. et al. (2018) Unit for metal refining. Pat. 120548, Ukraine. Int. Cl. B22D1/00 C21C7/072 C21C1/00 C21C7/00 C22B9/05 C22B9/20 [in Ukrainian].
12. Bezugliy, A.V., Nikolenko, A.V., Shevchenko, D.V. et al. (2021) Improvement of the process of conducting arc-free ferronickel melting in a six-electrode furnace. In: Proc. of the 16th Int. Ferro-Alloys Congress (INFACON XVI) 2021, 27-29 September 2021.
https://doi.org/10.2139/ssrn.392990213. Novikov, N.V., Kapran, I.I., Sokolov, K.D. et al. (2006) Innovative technological processes of electric furnace refining by progressive industrial methods. Information 2. Thermodynamic investigations of processes and technology of ladle desulfuration of electric furnace ferronickel by sodium carbonate. Advances in Electrometallurgy, 2, 36-39.
14. Melnik, S., Akreev, V., Prykhodko, S. et al. (2023) Degree of solid-phase reducing of iron from nickel ore oxides in tubular rotary furnace using thermal grade-coal as reducing agents. Modern Engineering and Innovative Technologies,1(29-01), 87-95. DOI: https://doi.org/10.30890/2567-5273.2023-29-01-069
15. Prykhodko, S., Shevchenko, D., Akreev, V. et al. (2023) Melting of complex laterite ores and selection of optimal reducing agents. Modern Eng. and Innovative Technologies, 1(29-01), 61-70. DOI: https://doi.org/10.30890/2567-5273.2023-29-01-067
16. Novikov, N.V., Kapran, I.I., Sokolov, K.D. et al. (2006) Innovation technological processes of electric furnace ferronickel refining by progressive industrial nethods. Pt 1. Thermodynamic properties of nickel-base systems and binary compounds. Advances in Electrometallurgy, 1, 36-40.
17. Novikov, N.V., Kapran, I.I., Sokolov, K.D. et al. (2006) Innovative technological processes of electric furnace ferronickel refining by progressive industrial methods. Pt 3. Processes and technology for refining ferronickel in acid and basic oxygen converters. Advances in Electrometallurgy, 3, 41-44.
18. Shevchenko, D.V., Zamkovoy, O.V., Ovcharuk, A.N. et al. (2021) Thermodynamic model of the process of desulfurization of a black ferronickel in a ladle. In: Proc. of the 16th Int. Ferro-Alloys Congress (INFACON XVI) 2021, 27-29 September 2021.
https://doi.org/10.2139/ssrn.393014319. Ovcharuk, A., Akreev, V., Prykhodko, S., Melnyk, S. (2023) Blowing of converter bath in ferronickel refining using one-nozzle and three- nozzle tuyeres. Modern Eng. and Innovative Technologies, 1(29-01), 71-86. DOI: https://doi.org/10.30890/2567-5273.2023-29-01-068.
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