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2001 №04 (05) 2001 №04 (07)

The Paton Welding Journal 2001 #04
The Paton Welding Journal, 2001, #4, 27-30 pages

About the form of hydrogen existence in welding fused fluxes

I.A. Goncharov1, A.P. Paltsevich1, V.S. Tokarev1, T.S. Veblaya2, N.P. Kharchenko2

1E.O. Paton Electric Welding Institute of the NASU 11 Kazymyr Malevych Str., 03150, Kyiv, Ukraine.
2Taras Shevchenko Kyiv National University, Kyiv, Ukraine

Abstract
The forms of hydrogen existence in welding fused flux AN-348A were examined using the methods of IR-spectroscopy, thermogravimetry and gas chromatography. As model substances the zeolite NaA and kaolin were used. A significant difference of flux AN-348A from the zeolite is shown by a nature of a thermal hydrogen desorption. It is established that the main part of the latter is dissolved in the flux examined during the process of furnace melting in the form of a hydroxyl and removed at heating above 800 oC.
Keywords: hydrogen, water, hydroxyl, fused flux, zeolite, kaolin, thermal desorption

References

1. Kirdo, I.V. (1950) About composition of gases surrounding the arc during submerged arc welding. Avtomaticheskaua 1, 50 - 59.
2. Pokhodnyaf I.K., Paltsevich, A.P., Golovko, V.G. et al. (1998) Technological and metallurgical methods of decreasing the absorption of hydrogen in welding. In: Coll, ofpapers of 1st Int. Conf of CIS on Welding Consumables, Krasnodar, June 22 - 26. Moscow: ОАО «АО Spetselektrod».
3. Brusnitsyn, Yu.D. (1958) About hydration of welding fused lluxes. W elding, Issue 1. Leningrad: Sudostroyemye.
4. Potapov, N.N. (1979) Fundamentals of selection of fluxes in welding of steels. Moscow: Mashinostroyeniye.
5. Kovach, Ya., Petrov, G.L. (1974) Investigation of hvdration and dehydration or acid lluxes tor the automatic arc welding of steels. In: Welding fluxes and slags. Kviv: Naukova Dumka.
6. Bctekhtin, A.G. (1950) Mineralogy. Moscow: Gosgeologizdat.
7. Novokhatsky, I.A. (1975) Gases in oxide melts. Moscow: Metallurgia.
8. Brusnitsyn, Yu.D., Vitol, E.I. (1963) About determination ol water in welding lluxes. W elding, Issue 6. Leningrad: Sudpromgiz.
9. Frolov, Yu.V. (1981) Fused flux as a hvdrogen source in welding. Aetomaticheskaya Svarka, 6. ol - o8.
10. Tsuboi, J., Terashima, II. (1973) The behavior of hydrogen in arc welding. J. JWS, 6, 544 - 553.
11. Paltsevich, A.P. (1998.) Chromatographic method of hydro¬gen content determination in components of electrode coatings. In: Coll, of papers of 1st Int. Conf, of CIS on Welding Consumables, Krasnodar, June 22 - 26. Moscow: ОАО «АО Spetselektrod».
12. Zarifiants, Yu.A., Kiselev, V.F., Khrustaleva, S.V. (1974) About inlrared spectra ol hydrate coating of oxides. In: Bound water in dispersed systems. Moscow: MSU.
13. Veblava, T.S., Kharchenko, N.P., Shevchenko, L.A. et al. (1981) Effect of method of granulation on structure of welding flux. Khim. Tekhnologiya, 3, 61 – 62.

Suggested Citation

I.A. Goncharov, A.P. Paltsevich, V.S. Tokarev, T.S. Veblaya, N.P. Kharchenko (2001) About the form of hydrogen existence in welding fused fluxes. The Paton Welding J., 04, 27-30.